The look on Angel's face as he walks into the Hyperion from his "restful" sojourn at the monastery. He's mourned Buffy, but now he's got this family that's just as important to him. Life goes on.
Cordelia, in TSiLA, after she recovers from Vocah's touch. She's finally accepted the visions, with a little bit of resignation and a lot of empathy.
Doyle trying to convince Angel to take up the cause in the series premiere. He's so uncomfortable and his reasons are unconventional, but there was something there. That was when I knew I was going to love this show.
"Because that's what lonely people do", in Lonely Hearts. I thought it was a lovely moment from DB.
aw I just remembered
"There's no place like...Willow?"
Wesley's face as Fred leaves at the end of "Billy" was another moment for me.
Oh, and Angel's stone-cold aim in ... the one where he shoots the psychic brain-wrapped dude in the back of the W&H car. Not only his aim, but the icy determination on his face.
Is it in "City Of..." when Angel does the dramatic leap into his car, and it's the wrong car?
Small moment with big meaning, from Angel:
"Is that it? Am I done?"
*sniff!*
Wesley's face as Fred leaves at the end of "Billy" was another moment for me.
Lilah's face when she shoots Billy is another good one.
Angel visiting Faith in prison.
Ooh, and also from "City Of...": "Can you fly?"